Waters
Passive sampling enables the monitoring of contaminants (micropollutants or biotoxins) in water (surface water, groundwater, coastal water…) for a short (at least 7 days) to long period (with an average field deployment of one month) for which no power, maintenance and supervision is required. An average of the concentration of collected contaminants is measured in the laboratory.
We offer a large range of passive samplers to collect very wide families of natural or synthetic molecules on surface water or on groundwater. Some passive samplers such as disks passive samplers and POCIS can uptake similar compounds depending on the good choice of the sorbent/membrane. For each passive sampler, we also have a format for groundwater analysis.
Passive samplers
- Passive samplers based on SPE disks are designed to provide TWA concentration of polar or non polar organic compounds as well as metals during the sampling period. This passive sampler is very simple of use to extract the contaminants.
- The Polar Organic Chemical Integrative Sampler (POCIS) is designed to provide the time weighted average (TWA) concentration of hydrophilic organic chemicals (pesticides, drug residues, Glyphosate & AMPA, EDCs…) during the sampling period. POCIS can be supplied with or without Performance Reference Compound (PRC). Historically developed for polar compounds, some applications have been developped for non polar compounds such as Perfluorinated compounds (PFAS) thanks to the right combination of sorbent/membranes.
- Silicone rubbers are the convenient tools for the uptake of non-polar contaminants such as PAHs or PCBs.
- Solid phase adsorption toxin tracking (SPATT) is a new monitoring tool that simulates the biotoxin contamination of filter feeding bivalves.
- Can generate a time-weighted average (TWA) concentration of the contaminants in water
- Deployable in harsh conditions
- No a priori preparation or supervision
- Detection of punctual contaminations
- Higher enrichment of contaminants
- Formats for surface water monitoring and for groundwater
AFFINISEP provides a complete range of sorbents for the retention of specific molecules or a family of contaminant for Pharmaceutical, Pesticides, Herbicides, Endocrine disruptors, glyphosate & AMPA, perfluorinated compounds as well as all necessary accessories such as holder, canister, manifold, ….
BRGM (French institute of geological survey) has evaluated the passive sampling of 42 pesticides for GROUNDWATER. Two types of passive samplers, a POCIS for polar pesticides, and a POCIS-MIP sampler equivalent to AFFINIMIP® POCIS Glyphosate were studied under low flow conditions as exist in groundwater. Calibrations took place in an experimental pilot filled with groundwater and with few metres water per day. AMPA and glyphosate had similar sampling rates for both tested water-flow values (1 m and 4 m per day), but that were lower than those obtained under stirring conditions by a factor 3 for glyphosate and a factor 7 for AMPA.
Estimating 42 pesticide sampling rates by POCIS and POCIS-MIP samplers for groundwater monitoring: a pilot-scale calibration, C. Berho, S. Robert, C. Coureau, E. Coisy, A. Berrehouc, L. Amalric, A. Bruchet, Environmental Science and Pollution Research (2020)
A polar organic chemical integrative sampler (POCIS) dedicated to glyphosate and its main degradation product aminomethylphosphonic acid (AMPA) have been developped from AFFINIMIP®SPE Glyphosate-AMPA. The laboratory calibration in a continuous water-flow-through exposure system show a sampling rates of 111 and 122 mL day-1 for glyphosate and AMPA respectively. This product is marketed as AFFINIMIP® POCIS GLYPHOSATE.
Laboratory calibration of a POCIS-like sampler based on molecularly imprinted polymers for glyphosate and AMPA sampling in water, , Anal Bioanal Chem 409: 2029 (2017).
A SPE sorbent based on Molecularly Imprinted Polymers (MIP) was developed for Glyphosate and AMPA to be tested as an integrative passive sampler (POCIS-LIKE) receiving phase.
New molecularly imprinted polymers (MIP) used as SPE clean up method and as a passive sampler receiving phase for the catchment of glyphosate and AMPA in water, C. Berho, B. Claude, L. Amalric, A. Togola, E. Grellet, S. Bayoudh, K. Puzio, P. Morin with a financial support of the French National Research Agency (ANR): ECOTECH ORIGAMI PROJECT, Poster presented at SETAC 2015.