Glyphosate
Glyphosate [(N-phosphonomethyl)glycine] is a non-selective broad-spectrum herbicide that is extensively used in agriculture. The biodegradation of Glyphosate (GLY) in the environment leads to aminomethylphosphonic acid (AMPA) as well as glufosinate.
- Pesticides and Herbicides /
- Glyphosate
AFFINIMIP® SPE Glyphosate - AMPA - Glufosinate - Cereals & Mineral Waters
Analysis of Glyphosate in Cereals
This application note shows analysis of Glyphosate, Glufosinate and AMPA of several experiments with an efficient clean-up with AFFINIMIP® SPE Glyphosate. Water and cereals were successfully tested for trace analysis conditions.
- Pesticides and Herbicides /
- Glyphosate
Analysis of Glyphosate and its metabolite in Juice by AFFINIMIP® SPE Glyphosate
Analysis of Glyphosate and its metabolite in Juice by AFFINIMIP® SPE Glyphosate
AFFINIMIP® SPE Glyphosate has been successfully used for a simple and fast cleanup of glyphosate, AMPA, and glufosinate from juice. AFFINIMIP® SPE Glyphosate shows excellent recoveries.
- Pesticides and Herbicides /
- Glyphosate
AFFINIMIP® SPE Glyphosate - AMPA - Glufosinate - Beers
Analysis of Glyphosate in Beers
AFFINIMIP® SPE Glyphosate has been successfully used for the enrichment and cleanup of glyphosate, AMPA, and glufosinate from blond beer and dark beer. AFFINIMIPÒ SPE Glyphosate demonstrated a high selectivity for the three molecules, giving good recoveries. In addition, the protocol has shown a good reproducibility with a relative standard deviation between 5% and 9% over 7 samples.
- Pesticides and Herbicides /
- Glyphosate
AFFINIMIP® SPE Glyphosate - AMPA - Glufosinate - Sea Water
Analysis of Glyphosate in Sea Water by AFFINIMIP® SPE Glyphosate
This application note describes the purification of glyphosate, AMPA, and glufosinate with 500mL of sea water at 200ng/L using AFFINIMIP® SPE Glyphosate via an automate Gilson 274 ASPEC Large Volume System. The method is done WITHOUT DERIVATIZATION saving a lot of time and trace analysis was done by LC-MS/MS. Recovery higher than 90% were observed for glyphosate and AMPA with a good repeatability.
- Pesticides and Herbicides /
- Glyphosate
Application note book AFFINIMIP®SPE Glyphosate
Our Application note book AFFINIMIP®SPE Glyphosate collects main useful information about :
AFFINIMIP® SPE Glyphosate description
Application notes for several complex matrices
Tested with several analytical methods with or without derivatization
Analytical conditions and transitions for LC-MS/MS analysis without derivatization
Passive samplers application for glyphosate – AMPA
Related products (accessories)
- Determination of Glyphosate, AMPA and GLUFOSINATE WITHOUT derivatization AFFINIMIP® SPE Glyphosate – AMPA – Glufosinate
And more applications are described in AFFINIMIP®SPE Glyphosate application note booklet with main matrices tested (Cereals, Tea, Juice, Honey, Water…)
- Cleanup and concentration of glyphosate and AMPA from 500mL of sea water was successfully carried out with AFFINIMIP® SPE Glyphosate with an excellent yield without derivatization. With the proposed method, limit of detection of 0.12 and 0.22 ng/L could be reached for Glyphosate and AMPA.
The challenge of detecting the herbicide glyphosate and its metabolite AMPA in seawater – Method development and application in the Baltic Sea; Marisa A.Wirth, Detlef E.Schulz-Bull, Marion Kanwischer, Chemosphere, Volume 262, January 2021, 128327, https://doi.org/10.1016/j.chemosphere.2020.128327
- AFFINIMIP® SPE Glyphosate was tested on different water matrices (mineral, groundwater, geothermal and sea). The protocol was first applied to mineral water spiked by GLY and AMPA at environmental concentration levels (25-750 ng L−1) using UPLC-MS after derivatization of GLY and AMPA by 9-fluorenylmethylchloroformate. The linear correlation between concentrations measured with and without SPE on MIP was proved. Furthermore, other extractions showed that high concentrations of metal ion interferents (lead(II), cadmium(II), and zinc(II)) in groundwaters did not reduce SPE performance of the MIP. Then, concentration assays were undertaken and brought noteworthy results, such as the recovery of 80% GLY and AMPA from groundwater spiked at 10 ng L−1 and concentrated 100 times. For this purpose, ion exclusion chromatography hyphenated to mass was applied without previous derivatization of the analytes. The same concentration factor and analytical method were applied to 100 ng L−1 spiked sea water with recoveries of 96% for GLY and 121% for AMPA.
Preliminary recovery study of a commercial molecularly imprinted polymer for the extraction of glyphosate and AMPA in different environmental waters using MS, B. Claude, C. Berho, S. Bayoudh, L. Amalric, E. Coisy, R. Nehmé, P. Morin, Environ Sci Pollut Res, 24: 12293 (2017).
- New molecularly imprinted polymers (MIP) used as SPE clean up method and as a passive sampler receiving phase for the catchment of glyphosate and AMPA in water, C. Berho, B. Claude, L. Amalric, A. Togola, E. Grellet, S. Bayoudh, K. Puzio, P. Morin with a financial support of the French National Research Agency (ANR): ECOTECH ORIGAMI PROJECT, Poster presented at SETAC 2015.
A SPE sorbent based on Molecularly Imprinted Polymers (MIP) was developed for Glyphosate and AMPA to be tested as an integrative passive sampler (POCIS-LIKE) receiving phase.